The smaller the number, the tighter the exit diameter. The .660" ED choke is tighter than the .665" which is tighter than the .670".
Theoretically, a tighter E.D. choke should throw a tighter pattern, but that's mostly hogwash since each gun/choke/load combo will pattern differently. Also, it's possible to over-choke certain loads which has a negative effect on your pattern and actually make it less dense.
Reading these boards will give you a good idea what certain gun/choke/load combo's are capable of, but the only true way to determine the best choke/load is to do your own pattern testing and make an informed decision from the results.
Good luck, and post your pattern pic's for all to see.